O-TBDPS d-glucosamine coupled with l-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes. © 2012 Elsevier Ltd. All rights reserved.
D-Glucosamine in a chimeric prolinamide organocatalyst for direct asymmetric aldol addition
De Nisco M.;
2012-01-01
Abstract
O-TBDPS d-glucosamine coupled with l-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes. © 2012 Elsevier Ltd. All rights reserved.File in questo prodotto:
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