A new synthetic catalyst, capable of acting like an enzyme in the accomplishment of direct aldol reactions, is presented. Excellent results, in terms of chemical yields and diastereo-/enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone to variously substituted benzaldehydes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Diastereo- and enantioselective direct aldol reactions in aqueous medium: A new highly efficient proline-sugar chimeric catalyst
De Nisco M.
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2011-01-01
Abstract
A new synthetic catalyst, capable of acting like an enzyme in the accomplishment of direct aldol reactions, is presented. Excellent results, in terms of chemical yields and diastereo-/enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone to variously substituted benzaldehydes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.File in questo prodotto:
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