Various terminal olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields by potassium permanganate oxidation. The reaction is also highly chemoselective in the presence of differently protected hydroxy groups and can be utilised for the preparation of polyfunctional compounds such as polyols.
New functionalised hydroxymethyl ketones from the mild and chemoselective KMnO4 oxidation of chiral terminal olefins
BONINI, Carlo Cesare;CHIUMMIENTO, Lucia;FUNICELLO, Maria;LUPATTELLI, Paolo;
2006-01-01
Abstract
Various terminal olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields by potassium permanganate oxidation. The reaction is also highly chemoselective in the presence of differently protected hydroxy groups and can be utilised for the preparation of polyfunctional compounds such as polyols.File in questo prodotto:
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