The oxidation of 2,6-diaminopyridine in acetonitrile-LiClO4 at a platinum electrode leads to the formation of two different films (I and II), depending on the deposition potential. Electroanalytical investigations revealed an ECE mechanism operating for film I formation and provided evidence for nucleation and growth in film II deposition. UV and ESCA spectroscopic characterization revealed the different natures of the films.
Electrosynthesis and analytical characterization of films obtained by oxidation of 2,6-diaminopyridine
GUERRIERI, Antonio;
1991-01-01
Abstract
The oxidation of 2,6-diaminopyridine in acetonitrile-LiClO4 at a platinum electrode leads to the formation of two different films (I and II), depending on the deposition potential. Electroanalytical investigations revealed an ECE mechanism operating for film I formation and provided evidence for nucleation and growth in film II deposition. UV and ESCA spectroscopic characterization revealed the different natures of the films.File in questo prodotto:
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