Starting from (S)-1,1′-binaphthol, a series of ten novel enantiopure 1,1′-binaphthylazepine-based aminoalcohols and diamines 1a-1j were efficiently prepared and fully characterized. These derivatives, having either only an atropisomeric bridged-binaphthyl backbone or an additional stereogenic carbon center, can be interesting ligands for asymmetric catalysis

1,1’-Binaphthylazepine-based Ligands for Asymmetric Catalysis. Part I: Preparation and Characterization of Some New Aminoalcohols and Diamines

SUPERCHI, Stefano;ROSINI, Carlo
2001-01-01

Abstract

Starting from (S)-1,1′-binaphthol, a series of ten novel enantiopure 1,1′-binaphthylazepine-based aminoalcohols and diamines 1a-1j were efficiently prepared and fully characterized. These derivatives, having either only an atropisomeric bridged-binaphthyl backbone or an additional stereogenic carbon center, can be interesting ligands for asymmetric catalysis
2001
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11563/17363
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