Starting from (S)-1,1′-binaphthol, a series of ten novel enantiopure 1,1′-binaphthylazepine-based aminoalcohols and diamines 1a-1j were efficiently prepared and fully characterized. These derivatives, having either only an atropisomeric bridged-binaphthyl backbone or an additional stereogenic carbon center, can be interesting ligands for asymmetric catalysis
1,1’-Binaphthylazepine-based Ligands for Asymmetric Catalysis. Part I: Preparation and Characterization of Some New Aminoalcohols and Diamines
SUPERCHI, Stefano;ROSINI, Carlo
2001-01-01
Abstract
Starting from (S)-1,1′-binaphthol, a series of ten novel enantiopure 1,1′-binaphthylazepine-based aminoalcohols and diamines 1a-1j were efficiently prepared and fully characterized. These derivatives, having either only an atropisomeric bridged-binaphthyl backbone or an additional stereogenic carbon center, can be interesting ligands for asymmetric catalysisFile in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
Tet_Asymm_2001_1235.pdf
solo utenti autorizzati
Descrizione: pdf finale
Tipologia:
Pdf editoriale
Licenza:
DRM non definito
Dimensione
92.61 kB
Formato
Adobe PDF
|
92.61 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
