We report the first asymmetric synthesis of trans optically active (+) C2 1,3-bisarylepoxide of calix[4]arene in excellent chemical yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane.
Novel chiral calix[4]arenes by direct asymmetric epoxidation reaction
BONINI, Carlo Cesare;CHIUMMIENTO, Lucia;FUNICELLO, Maria;LUPATTELLI, Paolo;
2008-01-01
Abstract
We report the first asymmetric synthesis of trans optically active (+) C2 1,3-bisarylepoxide of calix[4]arene in excellent chemical yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane.File in questo prodotto:
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