Influence of mucilage from seeds of chia (Salvia hispanica L.) as an amendment, on the sorption-desorption of herbicides in agricultural soils

The objective of this work was to determine the effect of the mucilage extracted from chia Chia seeds (Salvia hispanica L.) as soil amendment on soil physical properties and on the sorption-desorption behaviour of four herbicides (MCPA, Diuron, Clomazone and Terbuthylazine) used in cereal crops. Three soils of different texture (sandy-loam, loam and clay-loam) were selected, and mercury intrusion porosimetry and surface area analysis were used to examine changes in the microstructural characteristics caused by the reactions that occur between the mucilage and soil particles. Laboratory studies were conducted to characterise the selected herbicides with regard their sorption on tested soils added or not with the mucilage. Mucilage amendment resulted in a reduction in soil porosity, basically due to a reduction in larger pores (radius > 10 µm) and an important increase in finer pores (radius < 10 µm) and in partcles’ surface. A higher herbicide sorption in the amended soils was ascertained when compared to unamended soils. The sorption percentage of herbicides in soils treated with mucilage increased in the order; sandy-loam < loam < clay-loam. The increase in the organic carbon content upon amendment and the natural clay content of the soils are revealed to be responsible for the higher adsorption of Diuron when compared with Terbuthylazine, Clomazone and MCPA. Desorption of the herbicides was higly inhibited in the soils treated with mucilage; only Terbuthylazine showed a slight desorption in the case of loam and clay loam-soils. This study leads to the conclusion that mucilage from Chia seeds used as soil conditioner can reduce the mobility of herbicides tested in agricultural soils with different physico-chemical properties.