The Paternò-Büchi reaction between benzaldehyde and 2,3-dihydrofuran can be performed within the cavity of NaY zeolite. An increased stereoselectivity has been observed. When the reaction was performed with substituted benzaldehyde derivatives, different stereoselectivity has been observed. The stereoselectivity can be understood assuming an interaction in the biradical intermediate between the HSOMO and the LSOMO.
The diastereoselctivity of the Paternò-Büchi reaction between 2,3-dihydrofuran and aromatic carbonyl compounds in organized medium
D'AURIA, Maurizio;
2016-01-01
Abstract
The Paternò-Büchi reaction between benzaldehyde and 2,3-dihydrofuran can be performed within the cavity of NaY zeolite. An increased stereoselectivity has been observed. When the reaction was performed with substituted benzaldehyde derivatives, different stereoselectivity has been observed. The stereoselectivity can be understood assuming an interaction in the biradical intermediate between the HSOMO and the LSOMO.File in questo prodotto:
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