Abstract Low temperature NMR spectra show that the rotational ground state of N,N-diisopropyl-1-naphthylamine is perpendicular whereas that of its isomer (N,N-diisopropyl-2-naphthylamine) is planar: their rotational barriers have been measured (15.4 and 6.3 Kcal/mol respectively).
Conformational Studies by Dynamic Nuclear Magnetic Resonance. Part 29.Interchange of Symmetry between the Ground and Excited Rotational States of the Isomeric N,N-Diisopropylnaphthylamines.
CASARINI, Daniele;
1984-01-01
Abstract
Abstract Low temperature NMR spectra show that the rotational ground state of N,N-diisopropyl-1-naphthylamine is perpendicular whereas that of its isomer (N,N-diisopropyl-2-naphthylamine) is planar: their rotational barriers have been measured (15.4 and 6.3 Kcal/mol respectively).File in questo prodotto:
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