The direct, non ex post synthesis of a novel phthalocyanine decorated with eight thiohexyl-nido-carborane functions, nido-[H2MCHESPc]K8, where the anionic polyhedra are in the form of K+ salt, is reported and discussed. The solution properties of this compound, including the unprecedented exchange between the pyrrolic protons and the peripheral alkali-metal ions, are also analyzed.
Symmetrically Substituted nido-Carboranyl-Phthalocyanines: Facile Synthesis, Characterization, and Solution Properties. Evidence for Intra-and Intermolecular H+/K+ Exchange
ROSA, Angela Maria;PEPE, Antonietta;RICCIARDI, Giampaolo
2011-01-01
Abstract
The direct, non ex post synthesis of a novel phthalocyanine decorated with eight thiohexyl-nido-carborane functions, nido-[H2MCHESPc]K8, where the anionic polyhedra are in the form of K+ salt, is reported and discussed. The solution properties of this compound, including the unprecedented exchange between the pyrrolic protons and the peripheral alkali-metal ions, are also analyzed.File in questo prodotto:
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